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- فارسی
A modified electrode using carboxylated multiwalled carbon nanotubes and 1-butyl-2,3- dimethylimidazolium hexafluorophosphate ionic liquid for a simultaneous hazardous textile dye sensor
B. Rezaei, H. Khosropour, A.A. Ensafi,
This research attempted to develop a simultaneous, sensitive and low-cost electrochemical sensor
for acid blue 29 (AB 29) and mordant yellow 10 (MY 10) determination which are textile dye pollutants in
industrial waste waters. Therefore, the first electrochemical sensor has been developed for their
simultaneous determination by modifying a glassy carbon electrode (GCE) with a composite consisting
of 1-butyl-2,3- dimethylimidazolium hexafluorophosphate ([bmmim]PF6) 98% as an ionic liquid (IL) and
carboxylated multiwalled carbon nanotubes (CMWCNTs). Direct electrochemical oxidation of AB 29 and
MY 10 at the modified electrode showed two peak currents that were significantly improved due to the
presence of the ionic liquid–carboxylated multiwalled carbon nanotube-glassy carbon electrode
(IL/CMWCNT-GCE). The electrochemical signals improved due to the optimization of different
parameters affecting the sensitivity such as pH, electrode composition, scan rate, accumulation
potential and time. Individual and simultaneous determinations were performed by differential pulse
voltammetry (DPV) under optimum conditions. The linear dynamic ranges of 0.10–25 mmol L-1, with a
detection limit of 0.06 mmol L-1 for AB 29, and 0.6–30 mmol L-1, and a detection limit of 0.5 mmol
L-1 for MY 10, were achieved. Finally, the proposed modified electrochemical sensor was utilized for
individually and simultaneously detecting AB 29 and MY 10 in wastewater samples.