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Kinetic spectrophotometric determination of traces of sulphite

Authors: AFSANEH Safavi, AA Ensafi
Publication date: 1991/11/5
Journal name: Analytica chimica acta
Volume: 252
Pages: 121-126
Publisher: Elsevier
 
Abstract A method for the determination of sulphite is based on the addition reaction of
sulphite with Brilliant Green at pH 7 and 25 C. The decrease in absorbance of Brilliant Green
(λ max= 615 nm) over a fixed time is proportional to the concentration of sulphite over the
range of 10–1200 ng ml− 1. The limit of detection was found to be 5 ng ml− 1. Five replicate
analyses of a sample solution containing 1 μg ml− 1 sulphite gave a relative standard
deviation of 1%. The interferences of various ions were studied. A cation-exchange resin ...

 

Journal Papers
Month/Season: 
November
Year: 
1991

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