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A New Nanocomposite Based on Pt-rGO Embedded Polymelamine Formaldehyde Nanocomposite for Reduction of Carbon Dioxide
Hossein A. Alinajafi, Ali A. Ensafi, and B. Rezae
Electroanalysis 2021, 33, 1567 – 1577, https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/abs/10.100...
Abstract: Here, polymelamine formaldehyde was decorated on the surface of reduced graphene oxide whose surface was then electrodeposited with a sub-monolayer of platinum nanoparticles. The nanocomposite thus prepared was characterized using several spectroscopic methods. Using the nanocomposite as a potential electrocatalyst for carbon dioxide reduction, the products were detected by Raman spectroscopy, gas chromatography, 13C-NMR spectroscopy, and gas chromatography-mass spectrometry. The analytical results identified methanol as the main product of CO2 reduction. Moreover, analysis of the liquid products confirmed methanol as the predominant product with a current density of 0.4 mA/cm and a Faradaic efficiency of 93%.
Keywords: CO2 reduction to methanol · Polymelamine formaldehyde · Reduced graphene oxide · Pt nanoparticles